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KMID : 1024520030120030337
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Journal of the Environmental Sciences
2003 Volume.12 No. 3 p.337 ~ p.344
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Photodegradation of Pyrene, Chrysene and Benzo[a]pyrene in Water (I)
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Kim Ji-Yong
Huh Chul-Gu
Lee Min-Gyu
Kam Sang-Kyu
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Abstract
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The photodegradation of pyrene, chrysene and benzo［a］pyrene, that were similar in structure among poly-cyclic aromatic hydrocarbons (PAMs), were investigated in water irradiated with a low-pressure mercury lamp (wavelength of 253.7 nm and UV output of 1.35 10-3/J/s). The effects of several factors (t-BuOH, HCO-/ and pH) on photodegradation of above three PAHs were also examined. The photodegradation rates of PAHs decreased with increasing the concentration of t-BuOH, but decreased little with increasing the concentration of HCO-/ under the concentrations used in this study. The photodegradation rates of PAHs decreased with increasing pH, but their change were greater in case of pH increase from acid to neutral and were little in case of pH increase from neutral to base. The photodegradation rates of PAMs fitted a first-order kinetic model and their photodegradation rates decreased in the following sequences: pyrene>chrysene>benzo[a]pyrene among the PAHs used.
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KEYWORD
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Photodegradation, Pyrene, Chrysene, Benzo[a]pyrene, PAHs
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